不锈钢表面纳米SnO2/TiO2复合薄膜制备及防腐蚀性能     

王爱萍  周爱华 《中国海洋大学学报(自然科学版)》2020,50(3):81-87

采用溶胶凝胶法在不锈钢基体(304ss)上制备叠层式纳米SnO2/TiO2复合薄膜。使用X射线衍射(XRD)、扫描电子显微镜(SEM)表征纳米复合薄膜材料的晶体结构和微观形貌,通过交流阻抗技术(EIS)和极化曲线(Polarization Curves)电化学方法研究不锈钢表面纳米复合薄膜在模拟海水体系中的腐蚀行为。结果表明:制备叠层式纳米复合薄膜TiO2为锐钛矿型,SnO2为金红石型;不锈钢表面构筑叠层式纳米SnO2/TiO2复合薄膜颗粒粒径小,分布均匀且表面致密。电化学测试表明,叠层式纳米SnO2/TiO2复合薄膜阻抗值高于TiO2薄膜,且对不锈钢基体阳极反应有明显钝化过程,具有良好防腐蚀性能;同时叠层式纳米SnO2/TiO2复合薄膜存在最优叠加SnO2层数,叠加3层SnO2的纳米SnO2/TiO2复合薄膜电极防腐蚀性能最佳。  相似文献   

预制空心保温剪力墙试验研究及延性分析          下载免费PDF全文

陈哲贤  刘文燕  杨森  何文福  刘威 《世界地震工程》2022,38(3):048-58

为解决传统的预制实心剪力墙结构自重大以及运输不便等不足,并避免预制夹心剪力墙内外页墙板的连接问题,提出一种预制空心保温剪力墙（PHISW）结构。为研究PHISW的抗震性能,对2个剪力墙试件进行低周反复荷载试验。试验结果表明:PHISW破坏模式以弯曲破坏为主,承载力与现浇实心剪力墙相近,但延性系数略低。基于此采用ABAQUS建立数值分析模型,并分析了轴压比、暗柱箍筋直径和间距、暗柱纵筋配筋率以及空心率这四个参数对PHISW延性的影响。数值模拟结果表明:模拟分析的滞回曲线与试验结果吻合较好,轴压比、暗柱纵筋配筋率以及空心率对PHISW延性影响显著,暗柱配箍对PHISW延性的影响较小。建议轴压比设计值不大于0.4,暗柱箍筋直径不宜小于8 mm,箍筋间距不宜大于150 mm。暗柱纵筋配筋率建议取值为1.49%～3%,墙体空心率不宜大于25%。  相似文献   

提高人造金刚石钻头质量的有效途径   总被引：2，自引：1，他引：1       下载免费PDF全文

杨凯华段隆臣  胡国荣陈裕康 《探矿工程》1999,(1):42-44

采用真空气相沉积法在金刚石表面镀覆强碳化物金融或合金薄膜。该薄膜一方面与金刚石表面形成化学键合,另一方面大大提高与金融胎体的浸润性,从而明显增强金刚石在金融胎体中的结合强度,提高金刚石钻头性能和使用寿命。  相似文献   

纳米材料的发展及其展望   总被引：4，自引：1，他引：3  

周少红  甘树才 《世界地质》1999,18(3):100-104

介绍了纳米材料的研究现状及特点,对纳米组装材料,纳米结构材料、等纳米材料的研究进行了评述,并对２１世纪纳米材料的发展新动向提出展望。  相似文献   

基于模糊数学评价法优化凡纳滨对虾真空微波干燥工艺     

段少奇  吉宏武  张迪  董行  许佳音  宋文奎  刘书成  郝记明  苏伟明 《广东海洋大学学报》2021,(2)

【目的】探求真空微波干燥凡纳滨对虾的最佳工艺条件,以期为开发凡纳滨对虾即食食品提供技术参考。【方法】以新鲜凡纳滨对虾为原料,模糊数学感官评分为主要考察指标,在单因素试验基础上,选择载装量A、功率B、真空度C为自变量,利用响应面法和模糊数学评价法对真空微波干燥工艺进行优化。【结果】以感官评定为基础对真空微波干燥凡纳滨对虾的品质进行权重分析,得到权重集K=(色泽0.335,滋味0.305,香气0.215,组织质地0.145)。建立二次多项回归方程:Y=84.588+1.084A+1.409B+1.700C-7.353A²-8.793B²-13.860C²,显示载装量A、功率B、真空度C对感官评分有极显著影响(P<0.01)。通过响应面分析,得到真空微波干燥凡纳滨对虾的最佳工艺条件:载装量75 g,加热功率400 W,真空度0.08 MPa。在此条件下,真空微波干燥凡纳滨对虾品质良好,感官评分为(85.6±0.07)分,与预测值85.92分误差较小。【结论】响应面法优化凡纳滨对虾真空微波干燥工艺具有操作简单、优化条件精确、结果显示直观等优点;建立的回归方程能反映装载量等三个因素对指标的影响规律,并可进行实际预测。  相似文献   

渤中34-2油田复合射孔事故初探     

张飞  李君宝  王晓龙  金鑫  张彬奇  陈欣  徐鲲 《海洋地质译丛》2010,(2):100-104

渤中34-2油田P10井为一口调整井,属于正常温度、压力系统,孔隙度较低,近井带污染比较严重,完井射孔方式采用复合射孔。针对射孔作业中出现减震器上端油管挤瘪、RTTS封隔器水力锚和胶筒损坏、点火棒卡于封隔器芯管内等现象,从管柱设计、负压选择、管柱材质、现场施工管理等方面对此次事故进行分析,并提出相关建议,对射孔作业中类似事故的应对及处理有一定的指导意义。  相似文献   

吹填软土低位真空预压室内试验及其数值模拟     

杨爱武  潘亚轩  尚英杰  吴可龙 《岩土力学》2019,40(2):539-548

以天津滨海新区临港工业区吹填软土为试验材料,以普通型竖向排水板、改进型竖向排水板及改进型横向排水板进行室内低位真空预压试验。结果表明,利用普通型竖向排水板进行低位真空预压试验,在真空-堆载联合作用下,28 d表层土体强度达到10 kPa,但中间土体强度偏低,整体呈两边硬中间软的夹心层;以改进型竖向排水板进行低位真空预压试验,前10 d土体强度增长与普通型竖向排水板试验接近,后期土体强度增长明显比前者快,28 d表层土体强度达到12 kPa,中间土体强度略有提高,但整体均匀性仍较差;以改进型横向排水板进行低位真空预压试验,28 d表层土体强度达到11 kPa,强度增长比改进型竖向排水板试验慢,但中部土体强度和整体均匀性均优于改进型竖向排水板试验。基于上述试验成果,运用有限元模拟低位真空预压试验过程,计算沉降量和孔隙水压力并与实测数据对比,发现两种竖向排水板试验计算结果与实测数据吻合较好,改进型横向排水板试验稍差,但基本上都能反映低位真空预压过程中土体沉降量和孔隙水压力变化趋势。  相似文献   

Characterisation of nano magnesia–cement-reinforced seashore soft soil by direct-shear test     

Wei Wang  Chen Zhang  Na Li  Feifei Tao 《Marine Georesources & Geotechnology》2013,31(8):989-998

Abstract

In this study, the mechanical behaviour of nano magnesia–cement-reinforced seashore soft soil (NmC3S) was evaluated and characterised by the direct-shear testing of seashore soft soil (3S), cement reinforced seashore soft soil (C3S) and NmC3S. The comparison among these three types of soils indicates that NmC3S has greater shear strength and deformation modulus than C3S and 3S. The shear stress of both C3S and NmC3S increase significantly prior to a shear displacement of 1.0?mm, followed by a sharp decline before reaching the critical state. The failure displacement increases as the applied normal stress increases. NmC3S demonstrated greater friction angle than both C3S and 3S; however, the magnitude of its cohesion lies between that of C3S and 3S. Moreover, a mathematical model that describes the shear stress–displacement curve was proposed, which can effectively model the strain-hardening and strain-softening curves of these three types of clays. Finally, a generalised formula for capturing the stress–displacement behaviour of these three materials is presented with the explanations for the physical meaning of each parameter.  相似文献   

Mechanism test on inhomogeneity of dredged fill during vacuum preloading consolidation     

Yingguang Fang  Junwen Huang 《Marine Georesources & Geotechnology》2013,31(8):1007-1017

Abstract

First, this article presents a simulation experiment of hydraulic reclamation, and then a vacuum preloading (VP) test using the sedimentary soil obtained by the first experiment. In the VP test, the distribution and variation of different physico-mechanical parameters before and after the treatment were tested. According to the test results, the concept “non-Terzaghi soil” is proposed to explain the inhomogeneity and its mechanism rendered by “seepage separation.” And then a staged VP (SVP) drainage consolidation method has been introduced to improve the inhomogeneity and seepage curtain phenomena around prefabricated vertical drains (PVDs) during the consolidation. The test results demonstrate that the clogging problem around PVDs has been prevented and the consolidation efficiency has been promoted after the SVP test. It has been noticed that the cumulative drainage volume and the settlement displacement of SVP test were 27% and 24%, respectively, greater than that of VP test, and the soil tends to be more homogeneous. Moreover, it has been shown that the inhomogeneity degree of the permeability coefficient, unit weight, void ratio, water content, cohesion, internal friction angle, compression modulus, and the soil surface settlement in slurry after the SVP test were 3.10, 1.02, 1.03, 1.09, 2.30, 1.92, 1.19, and 1.02, whereas that after VP test was 397.27, 1.07, 1.40, 1.40, 4.74, 3.00, 1.76, and 1.22. Finally, the mechanism of SVP method has been discussed.  相似文献   

Newly developed technique and analysis solution to accelerate consolidation of ultrasoft soil     

Chen Geng  Shi Jiangwei  Chen Long 《Marine Georesources & Geotechnology》2017,35(2):292-299

Plastic vertical drainage is widely used in vacuum preloading for soft soil treatment. However, plastic vertical drainage has a number of disadvantages such as it only provides drainage paths in vertical directions and the distribution of soil strength is not uniform. A new technique, prefabricated vertical–horizontal drainage, was developed in this study to shorten the consolidation time of ultrasoft soil. Using one vertical drainage tube and four horizontal drainage tubes, prefabricated vertical–horizontal drainage provides drainage paths not only in vertical but also in horizontal directions. An analytical solution was derived to calculate the degree of soil consolidation when using the prefabricated vertical–horizontal drainage technique. Field tests were conducted to evaluate the effectiveness of prefabricated vertical–horizontal drainage and to verify the proposed analytical solution. It was found that consolidation time of soft clays using prefabricated vertical–horizontal drainage was 50% lower than plastic vertical drainage. Moreover, the average undrained shear strength of soil treated by the prefabricated vertical–horizontal drainage technique was approximately 30% larger than that treated by the plastic vertical drainage technique. The degree of soil consolidation estimated from the proposed analytical solution showed good agreement with field measurements. This implies that the proposed analytical solution can be used to directly estimate the degree of consolidation when the soil is treated by prefabricated vertical–horizontal drainage.  相似文献